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FCC catalysts
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Commercial Application of FCC Catalysts


1 General description

More than 30 kinds of FCC Catalysts with good bottom cracking ability ,high yield of light oils,low coke , better heavy metal resistance and high octane barrel are developed successfully in China, which active component include REY,REHY,USY,REUSY and MFI type zeolite.More than 100,000 ton/a FCC catalyst were manufactured in china and around 90% of domestic Chinese FCC Catalyst market was occupied by RIPP's technology to process different kind feedstock and run in different types of FCC units,such as in all SINOPEC subsidiary companies-BeiJing Yanshan company,QiLU company,Shanghai Gaoqioa company,Jinling company,Maoming company. Tianjin company,Changling company,Guangzhou company, Anqing company,Jingmen company,Luoyan company,SINOPEC JiuJiang company,JiNan company, WuHan company, Changzhou company, Beihai company, FuJian petrochemical Company Limitted (FPCL)ect.) and 29 refineries in CNPC  (mainly include Fushun company ,LanZhou company,DaQing company,JinZhou company and JinXi company ,ect.)Further more, catalysts developed by RIPP were also successfully applied in SK Corperation  (gasoline and propylene mode,Indonesia,2003-2004),which have exhibited good gasoline yield and good bottom cracking ability.

2. Catalyst commercial expercial experience in WEPEC,China

 WEPEC located at Dalian city,Liaoning province,China,is a China-French joint venture petrochemical enterprise,in which a RFCCU with capacity as 2Mt/a process mainly feedstock as 30towt% VGO+70% DSAR from Saudi Arabia and Iran light and heavy oil. In the beginning,RFCCU catalysts were purchased from international market.

In 1998,the catalyst in the RFCCU of WEPEC was replaced using RIPP's .The comparison data process performance between the two kinds of catalysts show in the following Tables.  

Table 20 Feedstock Properties

Case
Reference
Our catalyst
Density(20oC),g/cm³
0.9136
0.9235
Viscosity,mm²/s
80¡æ,100¡æ
 
33.09
18.07
 
38.92
20.40
Pour point, oC
+28
+23
CCR, wt%
4.4
5.4
Refraction index(70oC)
1.4959
1.5049
Element composition ,m%
 
C
H
S
N
 
 
87.00
12.34
0.47
0.19
 
 
86.65
12.02
0.62
0.24
Metal content ,ppm
5.1
6.1
Ni
9.4
10.7
V
<0.1
<0.1
Cu
7.3
7.7
Fe
2.5
1.9
Na
 
 
Distillation
281
295
IBP
356
362
5%
384
386
10%
446
442
30%
506
499
50%
559(63.5%)
555(65.5%)
70%
 
 

Note:*30wt% VGO+70wt% DSAR Saudi Arabia M
Table 21 Product Yields
Case
Reference
Our catalyst
Feed rate,t/d
5763
6062
Product yields,wt%
 
 
Dry gas
4.32
3.84
LPG
13.13
13.95
Naphtha
49.11
49.49
LCO
20.13
20.38
Slurry oil
4.39
3.59
Coke
8.37
8.30
Loss +acidic gas
0.55
0.45
Total
100.0
100.00
Conversion,wt%
75.48
76.03
Light oil yield ,m%
69.24
69.87
Liquid product yield ,m%
82.37
83.82

3 Catalyst commercial experience in SK,Korea
The commercial application of HGY-2000R catalyst in RFCCU,Ulsan complex ,SK Corporation, Korea in the period from July 27,2002,to August 7,2002. During the application ,FCCU ran smoothly and stably with daily catalyst make-up rate around 20 tons under feedstock as DSAR mixed with some DAO from Mid-east crude oil and unit throughput as 50,000 BPSD-54000,BPSD. The main commercial performances are shown in the following table 9 in brief.
Table 22 HGY-2000R catalyst commercial test results
Item
Unit
Base Case
CASE A
CASE  B
CASE C
Date
 
July 22-24
Aug. 1-3
July 31-Aug.2
Aug.5-7
Catalyst
 
Base*
RIPP
IPP
RIPP
Feed Rate
B/D
52714
52110
51469
53916
CFT
oC
208
209
205
204
Rx.Temp
oC
519
519
519
519
#2 Reg.Temp
oC
714
719
720
713
Cat M/U
T/Day
24.6
20.0
20.0
41.32
Rx.Cat Cir Rate
T/min
40.60
38.31
37.84
41.332
Cat Oil Ratio
Wt/wt
7.51
7.18
7.17
7.52
Coke Yield
Wt%
9.06
8.98
9.03
8.93
Cat.Cooler Duty
Gcal/h
40.4
39.6
40.0
38.2
Normalized Yield
 
C3
C4
LCN
HCN
Total Naphtha
LCO
SLO
Total
Minus C2
 
 
 
V%
V%
V%
V%
V%
V%
V%
V%
wt%
 
 
 
9.71
13.87
58.66
16.12
74.78
2.14
8.25
108.76
2.40
 
 
 
10.23
14.86
58.51
15.72
74.23
2.05
8.0
109.36
2.41
 
 
 
 
10.08
14.54
58.51
15.78
74.29
2.09
8.12
109.11
2.45
 
 
 
10.94
16.02
59.44
14.56
74.00
1.99
7.26
110.21
2.23
Feedstock
API
CCR
N
Ni
V
 
 
wt%
Wppm
Wppm
Wppm
 
20.77
3.93
1,739
4.90
6.80
 
20.90
4.00
1,845
5.67
7.90
 
20.77
4.17
1,944
5.90
8.23
 
21.47
3.43
1,697
3.37
4.27

QLCC. SINOPEC

Is the profession manufacturer of FCC catalysts with full advanced technology & equipments in China. With more than 30years of continuous efforts,QLCC.SINOPEC research and develop FCC catalysts of more than 30 species in 6 series(FCC  MGG  MIO  DCC  CPP Auxiliary)with production capacity of 45,000 MTs annually.

QLCC.SINOPEC

Develop the adaptability of FCC catalysts to be broad sense catalysts depending on characteristics of various feed stocks and various oil-refining equipments for various application around the word.
Hereinafter are our main FCC catalysts with typical characteristics:

Catalyst
Bottom
cracking
LPG
Yield
Light oil Yield
Octane number
enhancement
Gasoline
Yield
C3=,
C4=
selectivity
Iso-olefin
selectivity
Ni
Tolerance
V
tolerance
Catalytic cracking catalyst (FCC RFCC)
 
ZCM-7
 ..
 
 
 ..
 
 
 
 .
 .
 
RHZ-200
 .
 
 .
 ..
 
 
 
 
 
 
RHZ-300
 ..
 .
 
 
 .
 .
 
 ..
 .
 
MLC-500
 ...
 
 ..
 
 ...
 
 
 ..
 ..
 
ORBIT-3000
 ..
 
 ..
 
 ...
 
 
 ..
 ..
 
ORBIT-3300
 ...
 .
 ..
 ..
 
 
 
 ...
 ...
 ...
ORBIT-3600
 ...
 
 ...
 ..
 ...
 
 
 ...
 ...
 
COMET-400
  ...
 ...
 ..
 ..
 
 
 
 ..
 ..
 
ZC-7000
 ..
 
 ...
 
 ...
 
 
 ..
 ..
 
ZC-7300
 ..
 
 ..
 
 ...
 
 
 ..
 ..
 
Catalyst for maximum production of LPG and high octane gasoline (MGG ARGG)
 
RMG-2
 .
 ...
 
 ...
 ...
 
 
 .
 ..
 
RAG-1
 ..
 ...
 
 ...
 ...
 
 
 ..
 ..
 
RAG-6
 ..
 ...
 
 ...
 ...
 ..
 
 ..
 ..
 
Deep catalytic cracking catalyst(DCC-¢ñ DCC-¢ò)
 
CRP-1
..
 ...
 
 
 
 ...
 ..
 ..
 .
 
CIP-1
..
 ...
 
 
 
 ...
 ..
 ..
 .
 
CIP-2
..
 ...
 
 
 
 ...
 ..
 ..
 .
 
CIP-3
...
 ...
 
 
 
 ...
 ..
 . .
 .
 
Catalyst for maximum production of iso-olefin(MIO)
 
RFC-1
..
 ...
 
 
 
 ...
 ..
 ..
..
 
 
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